Highly-efficient synthesis of covalent porphyrinic cages via DABCO-templated imine condensation reactions.
نویسندگان
چکیده
We report a new approach to construct covalent porphyrinic cages with different spacer lengths, in which the cage compounds have been conveniently synthesized in quantitative yields, via DABCO-templated imine condensation reactions.
منابع مشابه
Templated synthesis of a large and flexible covalent porphyrinic cage bearing orthogonal recognition sites.
A large covalent cage incorporating two porphyrins attached by four long and flexible polyether chains each bearing two 3-pyridyl ligands was synthesized from a DABCO-templated olefin metathesis reaction. The X-ray structure of the cage with the DABCO coordinated inside the cavity to the two zinc(II) porphyrins reveals a highly symmetric structure.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 76 شماره
صفحات -
تاریخ انتشار 2014